Preheat oven to 400 degrees.
Spray 15 muffin cups with cooking spray.
In a large bowl, whisk together the flour, baking powder, salt and pepper. Add in the Parmesan, chicken and vegetables. Stir until everything is well coated with the flour mixture.
In a separate bowl, whisk together the buttermilk, melted butter and egg.
Add the buttermilk mixture to the flour mixture. Fold together with a wooden spoon or spatula until no streaks of flour remain.
Scoop muffin batter evenly into prepared muffin cups.
Bake for 17 - 20 minutes, or until a toothpick inserted in the center of a muffin comes out clean.