Preheat oven to 350 degrees. Spray a standard bundt pan with cooking spray and set aside.
Chocolate/Black Cake
Whisk together the flour, sugar, cocoa powder, baking soda, baking powder and salt.
With a hand or stand mixer, beat together the buttermilk, Guinness beer, oil, eggs, vanilla and black food coloring on low setting.
Add the flour mixture to the buttermilk mixture and beat until combined, then beat the cake batter for 4 minutes on medium speed.
Vanilla/Orange Cake
Beat the granulated sugar and butter with a hand or stand mixer at medium high speed until well blended.
Change the speed to low and add the egg, milk and vanilla. Change back to medium speed and mix well.
Whisk together the flour, baking powder and salt and add to the butter mixture. Beat batter for about 1 minute until smooth. Add the orange gel food color and mix again until well blended.
Cake Assembly
Using two muffin scoops, alternate scooping the chocolate/black cake batter and the vanilla/orange cake batter into the prepared bundt pan until all the batter is gone.
Tap the pan on the counter to make sure there are no bubbles.
Bake the cake for 35 - 40 minutes, or until the cake bounces back when lightly touched.
Allow the cake to cool in the pan for about 20 minutes. Invert the pan onto a cooling rack and allow the cake to continue cooling before serving.